Arsenic As 33

XRF Spectroscopy for Art Examination - ARSENIC
Arsenic-based pigments, orpiment (yellow) and realgar (orange-red), derived from naturally occurring arsenic sulfide, played a significant role in art history, they were widely used in particular for manuscripts. Starting from the 18th century synthetic arsenic-based pigments, such as Scheele’s Green and Emerald Green, were developed and used until the 19th century. While valued for their vibrant colors, these pigments were eventually discontinued due to their toxicity. This lesson focuses on identifying arsenic-based pigments using XRF spectroscopy. Objectives
  • Identify orpiment and realgar as arsenic-based pigments.
  • Analyze the spectral signals of arsenic in pigments using XRF spectroscopy.
Materials
  • Orpiment and realgar samples from Pigments Checker STANDARD.
  • XRF spectroscopy with Routine filter setup
Lesson Plan
  1. Introduction to Arsenic-Based Pigments
    • Discuss the historical use of orpiment and realgar.
  2. Hands-On Analysis of Orpiment and Realgar
    • Examine orpiment (As₂S₃) and realgar (As₄S₄) samples.
    • Compare spectral intensities of arsenic in orpiment and realgar.
   

To reinforce the concepts discussed here, we also provide a video lesson that visually walks through the key points of this topic. Watching the video alongside the text can help you better understand and apply these ideas in practice.

XRF Spectroscopy for Art Examination

The course XRF Spectroscopy for Art Examination introduces conservators, art historians, and scientists with interest in Art to the principles and practical applications of X-ray fluorescence (XRF) spectroscopy in the examination of artworks. The course starts with basic principles of XRF and gradually explores its role in identifying materials and methods used in the creation and conservation of art.

Course Objectives

  • Understand the fundamentals of XRF spectroscopy and how it applies to the analysis of art.
  • Learn the key features and limitations of XRF for examining art and archaeology.
  • Gain skills in interpreting XRF spectra to identify specific elements in paint layers, inks and metals.

Training 2026

Scientific Art Examination – Resources:
Getty Conservation Institute (GCI) – USA
The British Museum – Scientific Research Department – UK
Scientific Research Department – The Metropolitan Museum of Art, New York, USA
C2RMF (Centre de Recherche et de Restauration des Musées de France) – France
Rijksmuseum – Science Department – Netherlands