Zirconium Zr 40

XRF Spectroscopy for Art Examination - ZIRCONIUM

This lesson explores the role of zirconium in contemporary pigments, particularly zirconium silicate-based pigments. While zirconium is absent from historical and modern pigments, it plays a role in this specific class of high-performance pigments. The focus will be on praseodymium yellow, a zirconium silicate pigment used in ceramics and as an art material.

Objectives

  • Identify the significance of zirconium silicate in modern pigments.
  • Explore the role of doping in creating colored pigments, with praseodymium yellow as a case study.

Materials

  • Pigments Checker (Modern Art version, including praseodymium yellow).
  • Pure zirconium sample for reference.

Lesson Plan

  1. Introduction to Zirconium in Pigments
    • Discuss the absence of zirconium in historical pigments and its importance in modern zirconium silicate-based pigments.
    • Highlight praseodymium yellow as the key example.
  2. Doping and Pigment Formation
    • Describe how zirconium silicate is doped with praseodymium to produce yellow coloration.
  3. Spectrum Analysis
    • Analyze the XRF spectrum of pure zirconium and praseodymium yellow, noting the visibility of zirconium peaks even in small concentrations.