13, Aluminum, Al

XRF Spectroscopy for Art Examination - metals - aluminum

This lesson focuses on the analysis of aluminum-based metals, with a special emphasis on Italian coins. Aluminum, the lightest metal commonly used in artifacts, often appears as a pure material but contains trace elements that influence its properties. We will explore how these trace elements, either introduced intentionally or as impurities, impact the alloy’s characteristics.

Objectives:

  • Identify key trace elements commonly found in aluminum-based coins.

  • Understand the role of trace elements in enhancing the mechanical properties of aluminum.

  • Interpret XRF spectra to detect and distinguish between trace elements in aluminum coins.

  • Compare elemental composition between different coins and discuss potential sources of variation (e.g., mineral origin, recycling).

Materials:

  • Italian 10 lire (1958) and 5 lire (1982) coins

Lesson Plan:

  • Introduction to aluminum in artifact analysis and its relevance in numismatics

  • Examination of the 10 lire coin: aluminum core and trace elements (Mn, Fe, Ni, Cu, Zn, Ga, Zr, Pb)

  • Discussion of material origins, including bauxite-derived elements

  • Analysis of the 5 lire coin and the role of recycling in introducing bismuth

  • Comparison of XRF spectra with different filter setups to highlight elemental peaks

XRF Spectroscopy for Art Examination - metals - aluminum