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PBr 24 – chrome titanate
This page presents the Spectroscopic analysis of this pigment.
The pigment has been examined using XRF spectroscopy, Raman spectroscopy, FTIR spectroscopy, and Reflectance Spectroscopy. These complementary techniques provide valuable insights into the pigment’s composition and structure.
This page aims to show which analytical methods are most effective for identifying this pigment in artworks and historical materials. By comparing results across different techniques, it serves as a practical reference for Heritage Science, Conservation, and Pigment Analysis.
Manufacturer/ product code: Kremer / 43300
Chemical Description: Cr/Sb/Ti-oxide
Color: brown
Color Index: PBr 24
Date: from 1946
PBr 24, known as chrome titanate, is a synthetic inorganic pigment classified as a mixed metal oxide, typically composed of chromium, titanium, and sometimes antimony oxides. Developed in the mid-20th century, it was created to provide a stable, non-toxic alternative to traditional lead- or chromate-based brown and yellow pigments. Its hue ranges from warm yellow-brown to olive-brown, depending on the precise formulation and particle size.
As a pigment, PBr 24 exhibits excellent chemical and thermal stability. It is highly resistant to light, heat, acids, alkalis, and weathering, making it suitable for demanding applications in paints, coatings, ceramics, plastics, and industrial finishes. Its opacity is moderate, and it has a subdued, earthy color that blends well with other inorganic pigments to produce naturalistic browns and muted tones.
In modern artistic practice, PBr 24 is found in 20th- and 21st-century paintings, decorative finishes, and industrially produced colored media. It is particularly valued for its permanence and inertness, which make it reliable in conservation-sensitive contexts. Analytically, the pigment is easily detectable via XRF due to the presence of chromium and titanium, simplifying identification compared to many organic pigments. The presence of PBr 24 in an artwork is a clear marker of modern or contemporary materials, reflecting the 20th-century shift toward engineered pigments designed for durability and safety rather than traditional chromatic brilliance.
Reflectance Spectroscopy (350-950 nm)
Reflectance Spectroscopy (200-1250 nm)
Reflectance Spectroscopy (950-1700 nm)
XRF Spectroscopy
Raman Spectroscopy (1064 nm)
FTIR Spectroscopy (non-invasive )
Pigments databases
The Conservation & Art Materials Encyclopedia Online (CAMEO) is a comprehensive, searchable resource providing detailed technical information on materials (pigments), techniques, and tools used in art conservation, preservation, and scientific analysis.
IRUG (Infrared and Raman Users Group) Database
Open-access database of FTIR and Raman spectra for cultural heritage materials. Includes many historical pigments, dyes, and binders.

