Vanadium V 23

Vanadium, atomic number 23, holds some importance in the analysis of modern and contemporary art due to its presence in certain modern pigments. Its properties, such as the ability to produce bright, lightfast colors, make it particularly valuable for outdoor applications. This lesson explores vanadium’s role in art examination and its spectral characteristics in X-ray fluorescence (XRF) analysis, with a focus on the bismuth vanadate yellow pigment. Objectives
  • Understand the relevance of vanadium in modern and contemporary art.
  • Recognize the characteristics of vanadium’s X-ray spectral lines in XRF analysis.
  • Analyze spectral data from pure vanadium and bismuth vanadate yellow pigments using XRF spectroscopy.
  • Apply the low-kev filter setup for detecting vanadium in pigment samples.
Materials
  • XRF spectrometer with low-kev filter setup
  • Pure vanadium cube
  • Bismuth vanadate yellow pigment (from Pigments Checker)
Lesson Plan 1. Introduction to Vanadium in Art
  • Discuss the significance of vanadium in the context of modern and contemporary art.
  • Highlight its use in pigments, particularly bismuth vanadate yellow, for outdoor applications.
2. X-Ray Characteristics of Vanadium
  • Introduce the K-alpha (4.9 keV) and K-beta (5.4 keV) X-ray lines of vanadium.
  • Conduct XRF analysis with the low-kev filter setup, highlighting the high-intensity peaks achieved.
4. Analyzing Bismuth Vanadate Yellow
  • Perform XRF analysis on the bismuth vanadate yellow pigment using the Pigments Checker.
  • Explain the role of the low-kev filter setup in detecting vanadium peaks at lower counts.
 

To reinforce the concepts discussed here, we also provide a video lesson that visually walks through the key points of this topic. Watching the video alongside the text can help you better understand and apply these ideas in practice.

XRF Spectroscopy for Art Examination

The course XRF Spectroscopy for Art Examination introduces conservators, art historians, and scientists with interest in Art to the principles and practical applications of X-ray fluorescence (XRF) spectroscopy in the examination of artworks. The course starts with basic principles of XRF and gradually explores its role in identifying materials and methods used in the creation and conservation of art.

Course Objectives

  • Understand the fundamentals of XRF spectroscopy and how it applies to the analysis of art.
  • Learn the key features and limitations of XRF for examining art and archaeology.
  • Gain skills in interpreting XRF spectra to identify specific elements in paint layers, inks and metals.

Training 2026

Scientific Art Examination – Resources:
Getty Conservation Institute (GCI) – USA
The British Museum – Scientific Research Department – UK
Scientific Research Department – The Metropolitan Museum of Art, New York, USA
C2RMF (Centre de Recherche et de Restauration des Musées de France) – France
Rijksmuseum – Science Department – Netherlands